Dm. Tanenbaum et al., HIGH-RESOLUTION ELECTRON-BEAM LITHOGRAPHY USING ZEP-520 AND KRS RESISTS AT LOW-VOLTAGE, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 14(6), 1996, pp. 3829-3833
ZEP-520 and KRS resist systems have been evaluated as candidates for u
se in low voltage electron beam lithography. ZEP-520 is a conventional
chain scission resist which has a positive tone for over two orders o
f magnitude in exposure dose. KRS is a chemically amplified resist whi
ch can be easily tone reversed with a sensitivity similar to 8 mu C/cm
(2) at 1 keV. Both resist systems are shown to have sensitivities simi
lar to 1 mu C/cm(2) for positive tone area exposures to 1 keV electron
s. A decrease in contrast in 50 nm thick resist layers is seen when ex
posure voltage is lowered from 2 to 1 keV, indicating nonuniform energ
y deposition over the resist thickness. High resolution single pass li
nes have been transferred into both Si and SiO2 substrates at both low
and high voltages in each resist system without using multilayer resi
st masks. The ZEP-520 and KRS resists are shown to have resolutions of
50 and 60 nn, respectively, at 1 kV, within a factor of 2 of their hi
gh voltage resolutions under identical development conditions. A cusp
shaped etch profile in Si allows high aspect ratio 20 nm wide trenches
to be fabricated using these resists on bulk Si. Low voltage exposure
s have been used to pattern gratings with periods as small as 75 and 1
00 nm in ZEP-520 and KRS, respectively. Low voltage exposures on SiO2
show no indications of pattern distortion due to charging or proximity
effects. (C) 1996 American Vacuum Society.