STUDY OF REACTION AND KINETICS IN PYROLYSIS OF METHYL RICINOLEATE

Authors
HAN GB LIU ZY YAO SL YAN RF
Citation
Gb. Han et al., STUDY OF REACTION AND KINETICS IN PYROLYSIS OF METHYL RICINOLEATE, Journal of the American Oil Chemists' Society, 73(9), 1996, pp. 1109-1112
Citations number
13
Categorie Soggetti
Food Science & Tenology","Chemistry Applied
Journal title
Journal of the American Oil Chemists' Society → ACNP
ISSN journal
0003021X
Volume
73
Issue
9
Year of publication
1996
Pages
1109 - 1112
Database
ISI
SICI code
0003-021X(1996)73:9<1109:SORAKI>2.0.ZU;2-T
Abstract
The effects of pyrolysis temperature, space-velocity, and dilution rat io of starting materials on the reaction have been studied in the pyro lysis of methyl ricinoleate. The reaction parameters were optimized to obtain yield ranges of 25.8-26.7% for heptaldehyde and 45.7-46.5% for methyl undecenoate. The kinetic study showed that pyrolysis of methyl ricinoleate is a first-order reaction at 828-878 K, and the activatio n energy is 1.729 x 10(5) J/mol.