The co-evaporative Sb doping in Si molecular beam epitaxy was studied
with the emphasis on the crystalline quality of the films. By using re
flective high energy electron diffraction, cross-sectional transmissio
n electron microscopy, spread resistance profiling and secondary ion m
ass spectroscopy, it was found that doping growths at high substrate t
emperatures (greater than or equal to 500 degrees C) would degrade the
crystalline quality of the films. This degradation was attributed to
Sb segregation. In contrast, the films would retain good quality in do
ping growths at low substrate temperatures (< 500 degrees C) due to su
ppression of the segregation. Growth at low substrate temperature (350
-400 degrees C) plus post-annealing is recommended for growing Sb-dope
d Si films.