The advantage of a low voltage approach to lithography and surface mod
ification is that a more spatially localized energy deposition can be
achieved than with a focused high energy charged particle beam. Proxim
al probes, such as the scanning tunnelling microscope or atomic force
microscope with a conductive tip, are convenient ways to realize this
approach. We summarize here research performed over the past few years
at the Naval Research Laboratory directed towards materials studies a
nd lithographic fabrication of structures and devices using proximal p
robes.