IONIC-CONDUCTIVITY OF THE PBF2-CRYSTALS DOPED WITH ALKALI FLUORIDES(NAF EUTECTIC COMPOSITE AND PBF2 SINGLE)

Authors
TRNOVCOVA V FEDOROV PP BUCHINSKAYA II SOBOLEV BP
Citation
V. Trnovcova et al., IONIC-CONDUCTIVITY OF THE PBF2-CRYSTALS DOPED WITH ALKALI FLUORIDES(NAF EUTECTIC COMPOSITE AND PBF2 SINGLE), Inorganic materials, 32(10), 1996, pp. 1104-1107
Citations number
22
Categorie Soggetti
Material Science
Journal title
Inorganic materials → ACNP
ISSN journal
00201685
Volume
32
Issue
10
Year of publication
1996
Pages
1104 - 1107
Database
ISI
SICI code
0020-1685(1996)32:10<1104:IOTPDW>2.0.ZU;2-F
Abstract
Ionic conductivity of nominally pure PbF2 crystals, alkali-fluoride-do ped PbF2 crystals (0.5-1 mol % Li, Na, K, or Rb), and the 69 mol % PbF 2 + 31 mol % NaF eutectic composite was measured as a function of temp erature. The introduction of MF causes a sharp rise in sigma and a dec rease in activation energy; the effects of equal concentrations of KF and NaF are virtually identical. The room-temperature conductivity of the eutectic composite is 1.5 x 10(-4) S/cm.