Ca. Nichols et al., IONIZED PHYSICAL VAPOR-DEPOSITION OF CU FOR HIGH-ASPECT-RATIO DAMASCENE TRENCH FILL APPLICATIONS, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 14(5), 1996, pp. 3270-3275
The ionized physical vapor deposition technique is used to fill high a
spect ratio trenches with copper. This technique allows directional fi
lling of embedded features? known as damascene, by sputtering metal at
oms into a high density plasma. Large metal-atom ionized-Aux fractions
are achievable (approximate to 85%) leading to high directionality of
deposition at thr biased substrate. In this article, we report quanti
tative measurements of fill directionality of Cu using an inductively
coupled plasma (ICP) high density source. Copper is deposited into fai
rly aggressive (depth/width less than or equal to 1.5) damascene trenc
hes. Metal ion flux fractions are estimated from direct measurement of
the trench step coverage and compared to simulation. Estimates of the
Cu+/Ar+ density ratios are also made to understand the influence of a
pplied ICP power and Cu atom density (magnetron power) on fill directi
onality. It is found that at high magnetron powers (high copper atom d
ensities) the plasma becomes ''copper rich,'' where the flux of copper
ions exceeds that of the argon ions. At low magnetron power and high
ICP power, we find the trench fill to be highly directional. As magnet
ron power is increased, directionality suffers due to cooling of the p
lasma by higher copper atom flux. (C) 1996 American Vacuum Society.