D. Braunger et al., FLUX-ENHANCED GROWTH OF MULTISOURCE PHYSICAL VAPOR-DEPOSITED SRGA2S4-CE,CL ELECTROLUMINESCENT THIN-FILMS, Journal of crystal growth, 167(1-2), 1996, pp. 129-132
The flux-assisted deposition of the active phosphor layer in the highe
st efficiency, true blue (CIE coordinates of x = 0.14/y = 0.12) electr
oluminescent (EL) devices based on SrGa2S4:Ce,Cl is described. Luminan
ces of 78 cd/m(2) and luminous efficiencies of 0.017 lm/W at a transfe
rred charge of 1 mu C/cm(2) with 1 kHz/50 mu s bipolar square wave exc
itation were achieved. The influence of the coevaporated fluxes LiF an
d NaF in addition to the elements Sr, Ga, S, and the activator startin
g material CeCl3, on film growth is examined. The relation between Ga/
Sr, S/Sr, flux/Sr rates, and substrate temperature (T-Sub) on phase ho
mogeneity due to flux, crystal quality, film thickness, and device per
formance is described.