Aa. Burk et Lb. Rowland, THE ROLE OF EXCESS SILICON AND IN-SITU ETCHING ON 4H-SIC AND 6H-SIC EPITAXIAL LAYER MORPHOLOGY, Journal of crystal growth, 167(3-4), 1996, pp. 586-595
Specular 6H and 4H silicon carbide epitaxial layers have been grown us
ing optimized in situ pre-growth and steady state growth conditions. T
his study describes the impact of hydrogen and HCl etching on SIC surf
aces prior to growth nucleation. Propane and HCl overpressures are sho
wn to control the appearance of Si droplets and etch pits on SiC surfa
ces thereby strongly impacting subsequent epitaxial layer morphology.
After optimization of the SiC epitaxial growth process the majority of
the remaining morphological defects observed in SiC epitaxial layers
are shown to emanate from the substrate surface.