Formation of ordered tetragonal PtCo from epitaxial Pt(001)/Co(001) mu
ltilayers was observed via in situ X-ray diffraction measurements at f
our different annealing temperatures. The measured activation energy o
f formation of ordered PtCo is 2.1+/-0.2 eV. Ordering in the PtCo phas
e is not complete even after 1100 min annealing at 570 degrees C. Grow
th proceeds by nucleation of domains less than 10 Angstrom in thicknes
s, which thicken at a rate approximately proportional to the square ro
ot of time.