L. Adnane et al., COMPOSITION OF VANADIUM CARBIDES FORMED BY SOLIDIFICATION IN FE-V-C-MALLOYS - INFLUENCE OF ADDITIONS (M=AL, CU, MO), Mikrochimica acta, 1996, pp. 209-216
The solidification behavior of Fe-V-C-M alloys was studied by differen
tial thermal analysis. The composition of cubic vanadium carbides VCx
was analysed by quantitative electron probe microanalysis. The additio
n of a quaternary element (Mo, Al, Cu) induced changes in the crystall
ization path, the morphology of the carbides (Al) and the composition
of the vanadium carbides (Mo, Al). Moreover, the stoichiometry (x) of
the carbides depends on the nature of the addition.