GaA1As is a basic material in semiconductor technology and thus of gre
at interest for industrial research. Several Ga1-xAlxAs bulk samples o
f predefined composition as well as layered samples of well defined th
icknesses and composition were investigated. The experimental data are
analyzed with a computer program, which has been developed at the Ins
titute for Applied and Technical Physics at the Technical University o
f Vienna. Furthermore, analysis of the bulk samples using the program
PAP of Pouchou and Pichoir is carried out. An excellent agreement of b
oth correction procedures with the defined composition values is obtai
ned. The determined layer thicknesses also correspond well with the de
fined data. For our calculations the total K-peak of aluminum and the
total L-peak of gallium and arsenic were measured. Reducing the L-inte
nsities by the already published relative intensity factor for L alpha
radiation leads to less correspondence of the calculated k-ratios com
pared to the measured values. By additionally regarding the emerging L
beta intensities with partly much higher mass absorption coefficients
than the corresponding values for L alpha radiation a dramatic improv
ement is achieved.