M. Mannoh et al., COMPARISON OF ALTERNATE P-SOURCES TO PHOSPHINE IN THE METALORGANIC VAPOR-PHASE EPITAXY GROWTH OF P-ALGAINP, Journal of crystal growth, 145(1-4), 1994, pp. 158-163
Tertiarybutylphosphine (TBP) and bisphosphinoethane (BPE) have been st
udied as alternatives to phosphine (PH3) in the metalorganic vapor pha
se epitaxy (MOVPE) growth of Zn-doped p-type AlGaInP layers. Smooth su
rfaces were obtained for both organometallic phosphorus sources even f
or extremely low V/III ratios of 2 for BPE and 4 for TBP, compared wit
h 35 for PH3 at a growth temperature of 710 degrees C with a V/III rat
io as low as 75 exhibits strong photoluminescence intensity and a high
electrical activity of Zn which are comparable to those obtained for
the layers grown with PH3.