W. Bogdanowicz et Z. Bojarski, BETA'-SNSB SINGLE-CRYSTALS OBTAINED BY THE METHOD OF INCLINED FRONT CRYSTALLIZATION, Journal of crystal growth, 147(3-4), 1995, pp. 369-381
beta' phase plates of single crystals of SnSb alloy were obtained by u
sing a modification of the horizontal Bridgman method. It was ascertai
ned that during crystallization the single crystals grow in the upper
layer of the charge. It was found that the thickness of the single cry
stal (single crystal layer) and also its relative antimony content, de
pend on the growth rate and on the angle of inclination of the crystal
lization front relative to the growth direction. A model proposed for
the crystallization process permits the description of these relations
obtained. This method for obtaining single crystals, the inclined fro
nt crystallization (IFC) method, offers new possibilities for control
of chemical composition of plate single crystals of intermetallic phas
es, by varying the angle of inclination of the crystallization front.