In this paper, the characteristics of the kickout mechanism of diffusi
on have been detailed. Solutions have been presented under thermodynam
ic equilibrium conditions for an initial delta function impurity of tw
o types: (I) all atoms are initially on substitutional sites; (2) all
atoms are initially on interstitial sites. The solutions in the two ca
ses are shown to be different. Further the analysis is exact to first
order terms in g/r, where g is the generation rate and r the recombina
tion rate. They are therefore more accurate than any presented so far
and are applicable to dopants in silicon in the case of a dilute impur
ity.