Sk. Murad et al., DAMAGE-FREE AND SELECTIVE RIE OF GAAS ALGAAS IN SICL4/SIF4 PLASMA FORMESFET AND PSEUDOMORPHIC HEMTS GATE RECESS ETCHING/, Microelectronic engineering, 27(1-4), 1995, pp. 439-444
An apparently damage free and selective Reactive Ion Etching (RIE) pro
cess has been developed using a mixture of SiCl4/SiF4 plasma for etchi
ng GaAs/AlGaAs. Using a rf power of 9-12 W and hence a low dc bias of
less-than-or-equal-to 35 V, with a flow rate ratio of (2-3):9 sccm of
SiCl4:SiF4, the selectivities we obtained are extraordinarily high >50
00:1. No surface induced damage by this process can be detected. Raman
scattering measurements made on a heavily doped GaAs layer showed tha
t the etched surfaces improved on etching. Hall effect measurements on
pseudomorphic HEMT material structure showed no detectable modificati
on of the sheet carrier concentration even after 10 minute of continuo
us bombardment of the active layer. This SRIE has been applied to the
recessing of T-shaped gates and the lateral etching rate of these gate
s could be suppressed to <10 nm/min, resulting in a precise control of
the gate off-set and hence effective gate length.