Kg. Fertitta et al., HIGH-QUALITY GAN HETEROEPITAXIAL FILMS GROWN BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION, Journal of electronic materials, 24(4), 1995, pp. 257-261
In this paper, we describe the growth and characterization of high-qua
lity GaN heteroepitaxial films grown on basal-plane sapphire substrate
s using metalorganic chemical vapor deposition. The quality of these f
ilms is analyzed by a variety of methods, including high-resolution x-
ray diffraction, optical transmission spectroscopy, transmission elect
ron microscopy (TEM), room-temperature photoluminescence, and room-tem
perature Hall measurements. The x-ray diffraction full width at half m
aximum value of Delta Theta similar to 37 arc s is the narrowest repor
ted to date for any III-V nitride film on any substrate. The x-ray roc
king curves for similar to 0.48 mu m thick GaN/Al2O3 heteroepitaxial l
ayers exhibit Pendellosung fringes, indicating that even relatively th
in films can be of high quality. High-resolution TEM lattice images fu
rther attest to the excellent structural quality, showing the films to
be completely free of stacking faults. Furthermore, no evidence of co
lumnar growth is observed.