K. Doverspike et al., THE EFFECT OF GAN AND ALN BUFFER LAYERS ON GAN FILM PROPERTIES GROWN ON BOTH C-PLANE AND A-PLANE SAPPHIRE, Journal of electronic materials, 24(4), 1995, pp. 269-273
This paper presents a comparative study of the properties of GaN grown
by organometallic vapor phase epitaxy, using both a GaN and AlN buffe
r layer, as a function of sapphire orientation (c-plane vs a-plane). R
esults are presented for varying the thickness of the buffer layer, va
rying the growth temperature of the GaN film, and also varying the amm
onia/trimethylgallium mass flow ratio. The electron Hall mobilities of
GaN films grown on an AlN buffer layer were, in general, higher compa
red to films grown using a GaN buffer layer. In addition, growth on a-
plane sapphire resulted in higher quality films (over a wider range of
buffer thicknesses) than growth on c-plane sapphire. The room tempera
ture electron mobilities were also found to be dependent on, not only
the growth temperature, but also the ammonia/trimethylgallium mass flo
w ratio.