T. Miyoshi et al., SIMULTANEOUS DETERMINATION OF VARIOUS PES TICIDES IN RICE BY ION-TRAPGAS-CHROMATOGRAPHY MASS-SPECTROMETRIC (CHEMICAL-IONIZATION METHOD) ANALYSIS, Shokuhin Eiseigaku Zasshi, 36(2), 1995, pp. 274-282
Various pesticides in polished and unpolished rice were simultaneously
extracted and determined by ion-trap GC/MS with chemical ionization u
sing isobutane. Among 62 pesticides (25 organonitrogen pesticides, 25
organophosphorus pesticides, 7 organochlorine pesticides and 5 pyrethr
oid pesticides), almost all, except BHC, endrin and endosulfan, gave s
everal fragment ions in GC/MS (CI method) and the sensitivities were t
en times higher than in the EI mode. Recoveries of the pesticides spik
ed at 0.1 ppm in rice were more than 50% except for several pesticides
, and the detection limit for each was 0.005 ppm by the proposed metho
d.