P. Kurpas et al., MOVPE GROWTH OF GAINP GAAS HETERO-BIPOLAR-TRANSISTORS USING CBR4 AS CARBON DOPANT SOURCE/, Journal of crystal growth, 170(1-4), 1997, pp. 442-446
Carbon doping of GaAs with carbon tetrabromide (CBr4) in low pressure
MOVPE has been investigated and applied to the fabrication of GaInP/Ga
As HBTs. Especially the hydrogen incorporation and the associated acce
ptor passivation has been studied. The hydrogen found in single GaAs:C
layers is predominantly incorporated during cooling the sample under
AsH3 after growth. n-Type capping layers can block this H indiffusion
and GaAs:C base layers in HBTs show much lower H concentrations than G
aAs:C single layers without a cap. A further reduction of acceptor pas
sivation is possible by optimization of the growth procedure. First HB
Ts processed from layers with a base that was doped using CBr, show pr
omising DC and HF performance (beta = 45, f(T) = 26 GHz for 2 x 20 mu
m(2) devices).