We study the growth of InAs0.91Sb0.09 lattice matched on GaSb presenti
ng a bandgap of 0.29 eV (4.2 mu m) at 300 K. The layers are grown on (
100) GaSb and GaAs substrates at atmospheric pressure in a vertical re
actor MOVPE (metal organic vapor phase epitaxy) system using trimethyl
indium (TMIn), trimethylantimony (TMSb) and arsine (AsH3). We report t
he results on growth rate and InSb incorporation versus growth paramet
ers as temperature and TMSb partial pressure for different V/III ratio
s. Carrier density and mobility of InAsSb undoped layers are given. Op
tical photoconductivity measurements are presented with a wavelength c
ut off up to 5.4 mu m at 300 K, and the absorption by atmospheric CO2
at 4.25 mu m is clearly detected. The I-V curves of (n)InAsSb/(n and p
)GaSb heterojunctions are presented. At room temperature, the dark cur
rent for the n/n heterostructure is 70 mu A at -1 V, while the n/p jun
ction is ohmic.