Mi. Minguezmosquera et al., INVOLVEMENT OF COPPER AND ZINC IONS IN GREEN STAINING OF TABLE OLIVESOF THE VARIETY GORDAL, Journal of food protection, 58(5), 1995, pp. 564-569
The presence of metalochlorophyllic complexes of copper has been detec
ted in table olives showing the alteration known as green staining. Th
ese compounds are absent in the healthy fruit. The possible implicatio
n of fungicidal treatment of olive trees in this alteration has been s
tudied. No alteration was produced in table olives prepared with fruit
from trees with and without fungicidal treatment and the differences
found between copper levels in the fruit were not significant. The pos
sibility that the copper involved in this alteration is of extraneous
origin was, therefore, discarded. On the other hand, there were no sig
nificant differences in the levels of copper in random samples of frui
ts with and without green staining. Therefore, although the green-stai
ning alteration is the result of the formation of complexes of copper
with chlorophyll derivatives, it seems clear that the simple presence
in the fruits of copper, by itself, does not lead to the appearance of
green-staining.