Hf. Chuang et al., AN ELECTRICAL METHOD TO CHARACTERIZE THERMAL-REACTIONS OF PD GAAS ANDNI/GAAS CONTACTS/, Journal of electronic materials, 24(6), 1995, pp. 767-772
Capacitance-voltage (C-V) and current-voltage (I-V) measurements were
used to study the thermal reaction of Pd/GaAs contacts and Ni/GaAs con
tacts. The thickness of GaAs consumed by the metal/GaAs reaction durin
g annealing was calculated from C-V analyses and I-V analyses. For ann
ealing temperatures below 350 degrees C, the Schottky characteristics
of the diodes were good but the electrical junction moves into the GaA
s after annealing. The amount of junction movement was calculated dire
ctly from our measurements. The diffusion coefficients of Pd and Ni in
GaAs at 300 degrees C were estimated both to be around 1.2 x 10(-14)
cm(2)/s.