Well-defined oxide of GaAs can be used as a mask material for selectiv
e-area metalorganic molecular beam epitaxy (MOMBE) of GaAs. In this st
udy, the reaction between triethylgallium (TEG) and the GaAs oxide lay
er was studied using a quadrupole mass spectrometer (QMS) and an atomi
c force microscope (AM). Results of the QMS observation showed that TE
G was reflected on the GaAs oxide surface until the Start of desorptio
n of the GaAs oxide, and the GaAs oxide layer was desorbed from the wa
fer after a large time delay from the start of TEG supply. AFM images
showed that many holes appeared on the GaAs oxide surface during the d
esorption of the GaAs oxide. The effect of incident TEG upon the stabi
lity of the GaAs oxide mask is discussed.