We investigate the structural and optical properties of (In,Ga)As/GaAs
heterostructures induced by the low symmetry of the [311]A orientatio
n. High-resolution X-ray diffraction (HRDXD) measurements reveal the e
xistence of a shear-strained unit cell. The onset of relaxation in hea
vily strained structures leads to pronounced anisotropies and to satel
lite splittings in the X-ray diffraction patterns. Optical investigati
ons indicate that the impact of the piezoelectric fields on the ground
state energy is compensated for by In segregation. Nevertheless these
fields cause a pronounced reduction of the excitonic binding energy i
n the (311)A structures.