Sg. Hutchison et al., TITANIUM PRODUCTION IN A PLASMA REACTOR - A FEASIBILITY INVESTIGATION, Plasma chemistry and plasma processing, 15(2), 1995, pp. 353-367
The feasibility of producing titanium metal from titanium tetrachlorid
e in a thermal plasma under equilibrium and adiabatic expansion condit
ions has been theoretically investigated. Free energy minimisation and
adiabatic expansion calculations to simulate a nozzle expansion were
used to study the practicality of production. The crucial requirements
for the production of titanium powder from TiCl4 and H-2 appear to be
rapid quenching of the plasma gas at high temperature (e.g., 3700 K)
and appropriate reactant concentrations. Quenching of the plasma gas a
nd production of titanium powder can be achieved by adiabatic expansio
n through a nozzle. Preliminary experimental data indicate that titani
um powder of approximately 5 nm in size can be produced in an argon pl
asma using a nozzle expansion approach.