TITANIUM PRODUCTION IN A PLASMA REACTOR - A FEASIBILITY INVESTIGATION

Citation
Sg. Hutchison et al., TITANIUM PRODUCTION IN A PLASMA REACTOR - A FEASIBILITY INVESTIGATION, Plasma chemistry and plasma processing, 15(2), 1995, pp. 353-367
Citations number
17
Categorie Soggetti
Physics, Applied","Engineering, Chemical","Phsycs, Fluid & Plasmas
ISSN journal
02724324
Volume
15
Issue
2
Year of publication
1995
Pages
353 - 367
Database
ISI
SICI code
0272-4324(1995)15:2<353:TPIAPR>2.0.ZU;2-D
Abstract
The feasibility of producing titanium metal from titanium tetrachlorid e in a thermal plasma under equilibrium and adiabatic expansion condit ions has been theoretically investigated. Free energy minimisation and adiabatic expansion calculations to simulate a nozzle expansion were used to study the practicality of production. The crucial requirements for the production of titanium powder from TiCl4 and H-2 appear to be rapid quenching of the plasma gas at high temperature (e.g., 3700 K) and appropriate reactant concentrations. Quenching of the plasma gas a nd production of titanium powder can be achieved by adiabatic expansio n through a nozzle. Preliminary experimental data indicate that titani um powder of approximately 5 nm in size can be produced in an argon pl asma using a nozzle expansion approach.