Nitrogen (N) radical irradiated GaAs was investigated by Auger analysi
s and reflection high-energy electron diffraction. N radical beam irra
diation on GaAs causes an exchange of As atoms for N atoms, consequent
ly forming a GaN layer onto the GaAs surface without a Ga source. No d
egradation of the ZnSe layers was observed when they were grown on GaA
s substrates with GaN buffer layers. The current-voltage and capacitan
ce-voltage characteristics of p-ZnSe/p-GaAs heterodiodes are examined.
The necessary voltage for hole injection across the p-ZnSe/p-GaAs het
erojunction is reduced to about half when a thin GaN buffer layer is i
nserted into the junction.