Epitaxial CdF2 was grown on the coherent or relaxed CaF2/Si(111) by mo
lecular beam epitaxy. The structures were characterized by reflection
high-energy electron diffraction, Rutherford backscattering spectrosco
py and double-crystal X-ray diffraction. It was shown that the crystal
linity of the CdF2 layer grown on the CaF2/Si(111) structure, where th
e CaF2 was coherently grown on the Si, was quite good so as to obtain
51 are sec of full width at half maximum of X-ray diffraction.