Ion implantation technique has been used for the preparation of semico
nductor nanocrystals in SiO2 films deposited on semiconductor and quar
tz substrates. The structural properties of the films have been invest
igated by using low temperature optical spectroscopy and high resoluti
on electron microscopy, It is found that nucleation of the semiconduct
or phase can take place in the course of implantation with high ion do
se. The profile of both the concentration and the mean size of nanocry
stals over the film thickness is determined by the initial distributio
n of ions over the thickness and can be varied in a controlled manner
with the use of sequential ion implantations with various energies and
doses.