This study investigated the behavior of sorbic acid in shelf-stable me
ats with 0.91 water activity during processing (70 degrees, 80 degrees
, 90 degrees C) and accelerated storage (33 degrees, 45 degrees, 57 de
grees C). In meat systems stored at 70 degrees, 80 degrees and 90 degr
ees C, after approximately 0.5-3 days, the destruction rate of sorbic
acid diminished. This change in behavior (break) was probably caused b
y the limited availability of oxygen and/or the inhibitory action of n
onenzymatic browning products on sorbate destruction. Before the break
, the rate constants were found to be related to temperature, pH, the
acid used to adjust it and the humectants added to depress water activ
ity (NaCl, glycerol, the mixture NaCl 3.5% and glycerol). After the br
eak, none of the above mentioned effects were observed. In meat system
s stored at 33 degrees, 45 degrees and 57 degrees C the rate of destru
ction was constant with time. The rate constants of meat systems were
higher than the ones obtained for aqueous systems of similar compositi
on, revealing that meat components played an important role in the des
truction of sorbates.