Fl. Dickert et O. Schuster, SUPRAMOLECULAR DETECTION OF SOLVENT VAPORS WITH CALIXARENES - MASS-SENSITIVE SENSORS, MOLECULAR MECHANICS AND BET STUDIES, Mikrochimica acta, 119(1-2), 1995, pp. 55-62
Chemical sensors, based on highly mass sensitive QMB or SAW devices, c
oated with thin layers of calixarenes, enable the detection of organic
solvent vapours, especially halogenated or aromatic hydrocarbons, dow
n to a few ppm. Force field calculations allow the tailoring of these
sensor materials seeing that the predicted interaction energies betwee
n the host molecules and a large variety of analytes are linearly corr
elated to the measured sensor effects. These correlations and also BET
adsorption analysis prove the analyte recognition properties of these
calixarene coatings to be mainly based on host/guest inclusion princi
ples.