Ay. Polyakov et al., HYDROGEN AND NITROGEN PLASMA TREATMENT EFFECTS ON SURFACE-PROPERTIES OF GASB AND INGAASSB, Solid-state electronics, 38(10), 1995, pp. 1743-1745
P-i-n diodes of GaSb/InGaAsSb were treated in atomic hydrogen and atom
ic nitrogen flows in a microwave plasma crossed beams machine and in d
irect H-2 and N-2 plasma. The first type of treatment led to degradati
on of reverse currents of the diodes. Direct plasma treatments in H-2
alone also led to a deterioration of the surface properties. However,
combined treatment at 450 degrees C in direct H-2 and N-2 plasmas impr
oved the reverse currents and photoluminescence (PL) intensity by more
than an order of magnitude. Formation of a passivating GaN layer at t
he surface of GaSb depleted of Sb by preliminary intense H-2 treatment
is thought to be responsible for the effect.