K. Yasuda et al., LOW-TEMPERATURE GROWTH OF (100) HGCDTE LAYERS WITH DTBTE IN METALORGANIC VAPOR-PHASE EPITAXY, Journal of electronic materials, 24(9), 1995, pp. 1093-1097
Growth characteristics of (100) HgCdTe (MCT) layers by MOVPE at low te
mperature of 275 degrees C were studied using ditertiarybutyltelluride
as a tellurium precursor. Growths were conducted in a vertical narrow
-spacing growth cell at atmospheric pressure. Cd composition of MCT la
yers were controlled from 0 to 0.98 using dimethylcadmium (DMCd) flow.
The growth rate was constant for increase of DMCd flow. During the gr
owth, Cd was incorporated preferentially into the MCT layers. Enhancem
ent of Cd incorporation in the presence of Hg was also observed. Cryst
al quality and electrical properties were also evaluated, which showed
that high quality MCT layers can be grown at 275 degrees C. Strain in
CdTe layers grown at 425 and 275 degrees C was also evaluated. Lattic
e parameter of layers grown at 425 degrees C approached bulk value at
thickness of 5 mu m, while layers grown at 275 degrees C relaxed at 1
mu m The rapid strain relaxation of layers grown at 275 degrees C was
considered due to the layer growth on the strain relaxed buffer layer.
The effect of the thermal stress on the relaxation of CdTe lattice st
rain was also discussed.