J. Giess et al., THE ROLE OF SURFACE ADSORBATES IN THE METALORGANIC VAPOR-PHASE EPITAXIAL-GROWTH OF (HG,CD)TE ONTO (100) GAAS SUBSTRATES, Journal of electronic materials, 24(9), 1995, pp. 1149-1153
It has been established that a compound present as an impurity in the
propan-2-ol used in the preparation of GaAs (100) substrates for the m
etalorganic vapor phase epitaxy growth of (Hg,Cd)Te has a marked effec
t on the crystalline perfection and surface morphology of the resultin
g layers. In particular, the presence of this species, which contains
Na, ensures that (i) the epitaxial overgrowth is of(100) orientation w
ithout the need for ZnTe nucleation layers, and (ii) the density of py
ramidal hillocks on the surface can be reproducibly < 10 cm(-2).