Ka. Harris et al., ELECTRON-CYCLOTRON-RESONANCE PLASMA-ETCHING OF HGTE-CDTE SUPERLATTICES GROWN BY PHOTO-ASSISTED MOLECULAR-BEAM EPITAXY, Journal of electronic materials, 24(9), 1995, pp. 1201-1206
In order to form HgTe-CdTe superlattice diode arrays, a well-controlle
d etch process must be developed to form mesa structures on HgTe-CdTe
superlattice layers. Wet etch processes result in nonuniform, isotropi
c etch profiles, making it difficult to control etch depth and diode s
ize. In addition, surface films such as a Te-rich layer may result aft
er wet etching, degrading diode performance. Recently, a dry etch proc
ess for HgTe-CdTe superlattice materials has been developed at Martin
Marietta using an electron cyclotron resonance plasma reactor to form
mesa diode structures. This process results in uniform, anisotropic et
ch characteristics, and therefore may be a better choice for etching s
uperlattice materials than standard wet etch processes. In this paper,
we will present a comparison of etch processes for HgTe-CdTe superlat
tice materials using electron microscopy, scanning tunneling microscop
y, surface profilometry and infrared photoluminescence spectroscopy to
characterize both wet and dry etch processes.