The boundary element method is used to predict thermal stress profiles
in a two-dimensional, rectangular shaped GaAs crystal grown in a hori
zontal, two-zone Bridgman furnace. Stress is reported in terms of the
excess von Mises yield stress as a criterion that indicates the onset
of dislocations. It was observed that the temperature difference betwe
en the melting point and the ambient cold zone temperature is directly
proportional to the excess stress in the crystal, while the temperatu
re driving force in the hot zone has little influence. An increase in
the Peclet number and varying length of the adiabatic zone have little
effect on the predicted area of dislocations while decreasing the Blo
t number results in a larger region of the stress field that violates
the von Mises yield stress criterion. The model also predicts dislocat
ion-free Ge crystals for operating conditions which give rise to dislo
cations in GaAs due to the much higher critical stress of Ge compared
with GaAs.