K. Papadopoulou et Jm. Ames, PROPOSAL OF A MECHANISM FOR THE INHIBITION OF ALL TRANS-BETA-CAROTENEAUTOXIDATION AT ELEVATED-TEMPERATURE BY N-(2-PHENYLETHYL)-3,4-DIPHENYLPYRROLE, Food chemistry, 54(3), 1995, pp. 251-253
The rate constant for the loss of all-trans-beta-carotene heated in li
quid paraffin at 210 degrees C is reduced by a factor of 2.8 in the pr
esence of phenylalanine. N-(2-phenylethyl)-3,4-diphenylpyrrole is the
major non-volatile methanol-extractable thermal degradation product of
phenylalanine formed at 210 degrees C and a mechanism for its inhibit
ion of all-trans-beta-carotene autoxidation is proposed.