Dt. Grider et al., ULTRA-SHALLOW RAISED P-N JUNCTIONS FORMED BY DIFFUSION FROM SELECTIVELY DEPOSITED IN-SITU DOPED SI0.7GE0.3(), Journal of electronic materials, 24(10), 1995, pp. 1369-1376
In this paper, a novel raised p(+)-n junction formation technique is p
resented. The technique makes use of in-situ doped, selectively deposi
ted Si0.7Ge0.3 as a solid diffusion source. In this study, the films w
ere deposited in a tungsten halogen lamp heated cold-walled rapid ther
mal processor using SiCl2H2, GeH4, and B2H6. The microstructure of the
Si0.7Ge0.3 layer resembles that of a heavily defected epitaxial layer
with a high density of misfit dislocations, micro-twins, and stacking
faults. Conventional furnace annealing or rapid thermal annealing wer
e used to drive the boron from the in-situ doped Si0.7Ge0.3 source int
o silicon to form ultra-shallow p(+)n junctions. Segregation at the Si
0.7Ge0.3/Si interface was observed resulting in an approximately 3:1 b
oron concentration discontinuity at the interface. Junction profiles a
s shallow as a few hundred angstroms were formed at a background conce
ntration of 10(17) cm(3).