EFFECT OF CARBON-DIOXIDE ON THE ELECTRICAL-CONDUCTIVITY OF POLYETHYLENE GLYCOL-ALKALI CARBONATE COMPLEX FILM

A solid film consisting of triethylene glycol, K2CO3-polyethylene glyc ol of high mol. wt., was prepared on a sintered alumina substrate with a pair of golden electrodes and their electrical conductivity was mea sured. When CO2 gas was introduced into the air, the conductivity decr eased. This change was reversible. The sensitivity to CO2, designated as (change in conductivity caused by CO2)/(conductivity in air), was t he highest when a polyethylene glycol of mol. wt. 6000 was used. The s ensing mechanism was interpreted in terms of the change in concentrati on of the charge carrier K+ ion by CO2.