Ml. Brake et al., REACTIVE ION ETCHING IN THE GASEOUS ELECTRONICS CONFERENCE RF REFERENCE CELL, Journal of research of the National Institute of Standards and Technology, 100(4), 1995, pp. 441-448
This paper describes the results of using the GEC reference cell as a
reactive ion etcher. Silicon wafers with layers of polysilicon and sil
icon dioxide on crystaline silicon patterned with photoresist have bee
n investigated with fluorine and chlorine chemistries. Scanning electr
on microscopy (SEM), profilometry, and refraction techniques were used
to determine the etch parameters such as etch rate, uniformity and se
lectivity. The discharges are in general monitored by measuring the op
tical emission spectroscopy and the bias voltages. For fluorine chemis
tries, etch rates ranged from 5 nm/min to 177 nm/min, and for chlorine
chemistries, etch rates ranged from 25 nm/min to 90 nm/min. Depending
upon the discharge and chemistry conditions, similar etch rates and e
tch patterns of different GEC cells were obtained. Etch rates and rela
tive fluorine concentrations obtained from a commercial etcher were co
mpared to the GEC reference cell and were found to be similar although
the GEC cell generally gave lower etch rates than the commercial etch
er.