Recent experimental results on optical properties of GaN and related m
aterials are discussed. Photoluminescence data of free excitons for su
fficiently pure GaN samples demonstrate the dominance of excitonic rec
ombination well above room temperature. Transient PL data give a radia
tive lifetime of about 200 ps for the A-exciton at 2 K in strain-free
samples. A corresponding value of about 2 ns at room temperature is ex
trapolated. Radiative lifetimes for bound excitons are measured as abo
ut 250 ps for shallow donors and about 1.5 ns for shallow accepters. P
hotoluminescence spectra from the 2D electron gas at a GaN/AlGaN heter
ointerface are also demonstrated. (C) 1997 Elsevier Science Ltd.