M. Mashita et al., COMPARATIVE-STUDY ON CARBON INCORPORATION IN MOCVD ALGAAS LAYERS BETWEEN ARSINE AND TERTIARYBUTYLARSINE, Journal of crystal growth, 155(3-4), 1995, pp. 164-170
We have studied the carbon incorporation properties in MOCVD Al0.7Ga0.
3As epilayers on differently oriented surfaces by using either arsine
or tertiarybutylarsine (TBAs). The present study has shown that the ca
rbon incorporation in the layers using TBAs is significantly lower tha
n that using AsH3 under higher V/III ratio and/or lower temperature co
nditions. The results also indicate that the carbon does not originate
in TBAs but in TMG and TMA. According to these results, the carbon in
corporation mechanism is discussed through analysis of reaction produc
ts by growth. A growth model in which As molecules rather than H atoms
act on the carbon elimination from the growth surface is presented.