S. Barton et al., MINORITY-CARRIER LIFETIME IN DOPED AND UNDOPED EPITAXIALLY GROWN N-TYPE CDXHG1-XTE, Journal of electronic materials, 24(11), 1995, pp. 1759-1764
The performance of infrared detectors made from CdxHg1-xTe (CMT) is re
lated to the lifetime of minority carriers in the material. Both photo
conductive and photovoltaic devices require long lifetimes for high pe
rformance. This paper compares lifetime measurements on epitaxially gr
own CMT layers which have been isothermally annealed to minimize the v
acancy concentration and are n-type due to native defects, residual im
purities, or deliberately added dopants. Layers grown by liquid phase
epitaxy (LPE), metalorganic vapor phase epitaxy (MOVPE), and molecular
beam epitaxy (MBE) have been considered, in all cases the same measur
ement system was used under the same low injection conditions. All lay
ers were of compositions required for operation in the 8 to 14 mu m wa
velength range. Comparisons have been made between undoped and indium
doped LPE layers and undoped and iodine doped MOVPE layers. It was hop
ed that a deliberately introduced donor impurity would give better con
trol of the n-type properties. The effect of passivation on the measur
ement of lifetime has also been considered, the results showing that a
surface with a native oxide is required to obtain the true bulk lifet
ime as has been seen previously for bulk material.