p-ZnO/n-ZnSe and p-ZnO/p-ZnSe/n-ZnSe structures were prepared by radic
al-beam getter epitaxy under different conditions. The structures were
characterized by current-light, I-V, C-V, and electroluminescence mea
surements. Depth profiles of oxygen and selenium were investigated by
secondary-ion mass spectrometry. The experimental data and the reporte
d electron affinities of ZnO and ZnSe were used to develop energy-band
models for the two types of heterostructure. The major defect species
present in zinc selenide were identified from the luminescence spectr
um of erbium, a spectroscopic probe introduced by ion implantation.