The molecular beam epitaxial growth of low temperature (LT) GaAs films
has been studied by real-time ellipsometry. A modification in a GaAs(
001) surface by cooling under a specific As-2 flux caused a change in
the ellipsometry data. The thermocouple reading of this change was use
d as a signature to indicate the reproducible substrate temperature fo
r the growth of LT-GaAs layers. The origin of this surface modificatio
n was studied by reflection high energy electron diffraction. The grow
th regimes of LT-GaAs layers were studied by real-time ellipsometry. T
he dielectric properties of the epitaxial layer and the critical thick
ness for epitaxial growth were extracted for various growth conditions
. The microstructure beyond the critical point was found to be compose
d of amorphous as well as crystalline forms of GaAs.