G. Coudenys et al., ATMOSPHERIC AND LOW-PRESSURE SHADOW MASKED MOVPE GROWTH OF INGAAS(P) INP AND (IN)GAAS/(AL)GAAS HETEROSTRUCTURES AND QUANTUM-WELLS/, Journal of electronic materials, 23(2), 1994, pp. 225-232
The shadow masked growth technique is presented as a tool to achieve t
hickness and bandgap variations laterally over the substrate during me
talorganic vapor phase epitaxy. Lateral thickness and bandgap variatio
ns are very important for the fabrication of photonic integrated circu
its, where several passive and active optical components need to be in
tegrated on the same substrate. Several aspects of the shadow masked g
rowth are characterized for InP based materials as well as for GaAs ba
sed materials. Thickness reductions are studied as a function of the m
ask dimensions, the reactor pressure, the orientation of the masked ch
annels and the undercutting of the mask. The thickness reduction is st
rongly influenced by the mask dimensions and the reactor pressure, whi
le the influence of the orientation of the channels and the amount of
undercutting is only significant for narrow mask windows. During shado
w masked growth, there are not only thickness variations but also comp
ositional variations. Therefore, we studied the changes in In/Ga and A
s/P ratios for InGaAs and InGaAsP layers. It appears that mainly the I
n/Ga-ratio is responsible for compositional changes and that the As/P-
ratio remains unchanged during shadow masked growth.