Gl. Waytena et al., THE OPTIMIZATION OF THE DOUBLE MASK SYSTEM TO MINIMIZE THE CONTACT RESISTANCE OF A TI PT/AU CONTACT/, Journal of electronic materials, 26(2), 1997, pp. 90-96
The fabrication of Ti/Pt/Au ohmic contacts on diamond using two transm
ission line model masks during the photolithography step was modified
as a result of the adverse effects on the resistance from the rectifyi
ng lip created by the overlap of the two masks, and the possible inhib
ition of carbide formation due to the presence of oxygen on the diamon
d surface before metallization. The first modification consisted of de
creasing the rectifying lip by diffusing a small amount of Ti from ben
eath the contact defined by the first mask, and decreasing the overlap
of the two masks from 5 to 2 mu m, which is close to the minimum allo
wable by our photolithography techniques. The second modification cons
isted of the desorption of oxygen from the diamond surface using a hea
t treatment in vacuum and cool down in purified hydrogen. As a result
of these changes, the contact resistance was decreased by more than tw
o orders of magnitude from 8.1 x 10(-2) Ohm-cm(2) to 1.2 x 10(-4) Ohm-
cm(2).