Dc. Houghton et al., COMPARISON OF CHEMICAL BEAM EPITAXY AND METALORGANIC CHEMICAL-VAPOR-DEPOSITION FOR HIGHLY STRAINED MULTIPLE-QUANTUM-WELL INGAASP INP 1.5-MU-M LASERS/, Journal of crystal growth, 136(1-4), 1994, pp. 56-63
The performance and reliability of strained layer optoelectronic devic
es are in general limited by the integrity of metastable heterostructu
res. Misfit strain relaxation (and concomitant defects) can be avoided
if the structural stability is optimised and elevated temperature exp
osure minimized. Chemical beam epitaxy (CBE) holds great promise in st
rained layer epitaxy, since by reducing growth temperature the overall
thermal budget for epitaxy and processing can be significantly reduce
d. The design, epitaxial growth, fabrication and reliability issues re
lated to strain and strain-compensated multi-quantum well lasers are f
irst considered in order to determine the upper limits of compressive
or tensile strain permissible in such structures. The benefits of stra
in (both tensile and compressive) on threshold current density are rel
ated to the amount of strain in the wells (via the reduction of the Au
ger recombination coefficient) and the well width (via the optical con
finement factor). It is therefore the strain - well-width product for
the active region which is of key interest. In this survey the practic
al upper bound to stability is defined theoretically using an energy b
alance model, where the effect of strain compensation from oppositely
strained barrier layers, balances the strain in the quantum wells and
renders the multilayer stack ''strain neutral''. The susceptibility of
strained multilayers to defect injection through epitaxial growth and
subsequent device fabrication is determined by growth simulation. Usi
ng this model as a design tool we have investigated the structural sta
bility of a compressively strained multiple quantum well (MQW) laser t
hrough the concept of ''effective stress'' for misfit dislocation inje
ction. The upper limits for quantum well strain incorporation with and
without strain compensation are quantitatively defined in light of re
cent laser reliability data. The evolution of the driving force for mi
sfit strain relaxation is mapped out through a typical epitaxial growt
h sequence highlighting the points in the growth process of highest vu
lnerability to defect injection. These design concepts were used to op
timize structures for highly strained quantum wells (QWs) in strain co
mpensated InGaAs/InP MQW lasers. The stability of strain-compensated M
QW laser structures is demonstrated for devices grown by conventional
metalorganic chemical vapour deposition.