M. Yoshimoto et al., IN-SITU REFLECTION HIGH-ENERGY ELECTRON-DIFFRACTION OBSERVATION OF LASER-TRIGGERED GAP GROWTH IN CHEMICAL BEAM EPITAXY, Journal of crystal growth, 136(1-4), 1994, pp. 89-93
Surface reaction triggered by N2 laser irradiation onto adsorbed triet
hylgallium (TEGa) and reaction with phosphorus in chemical beam epitax
y (CBE) was studied by growth experiment and intensity change of refle
ction high-energy electron diffraction (RHEED). The growth rate shows
saturation with a high TEGa supply, which suggests that the adsorption
of TEGa on a surface is saturated. The change of RHEED oscillation wa
s different from that of a continuous reaction. The result showed that
the decomposition of TEGa and formation of GaP occur alternately unde
r continuous supply of TEGa and PH3.