In the present paper, energy transfer processes via the interface of m
olecular beam epitaxy (MBE) grown ZnSe/GaAs epilayers are investigated
by means of time-resolved photoluminescence spectroscopy. High excita
tion experiments show that an electron-hole plasma exists in free-stan
ding ZnSe layers only. By comparing the time-resolved luminescence pro
perties of ZnSe/GaAs heterostructures and of free-standing ZnSe layers
, we demonstrate which kind of energy transfer mechanism is predominan
t in heterostructures: At low excitation densities energy is transfere
d by re-absorption of the ZnSe luminescence. At higher excitation dens
ities, an ambipolar carrier diffusion via the ZnSe/GaAs interface is t
he dominating process.