Porod plots of the small-angle X-ray intensities scattered by porous s
ilicas that have undergone different coating processes show deviations
from the predicted constant asymptotic behaviour. The deviations are
ascribed to the effect of the coating film. We propose a constant-elec
tron-density model for these films. The theoretical scattering functio
n calculated from the model permits an estimate of the film thickness,
electron density and average number of coating molecules per unit are
a of the support.